The FDA later relaxed that policy and in 1978 approved a 50 percent solution of DMSO as a treatment for interstitial cystitis, a condition marked by painful urinary tract lesions that occurs predominantly in women. Rodney Marks was a 32-year-old astrophysicist doing research for the University of Chicago. A relatively unassuming bridge in Scotland holds a dark secret that has haunted the city of Glasgow, Scotland for years. To the relief of hospital administrators, the hazmat crew detected none of these chemicals in the emergency room. The investigation by the National Institute for Occupational Safety and Health had also found this amine and had suggested that it was a possible culprit, despite its minuscule levels in the autopsy samples. This woman, the paramedics reported, was 31 years old and had cervical cancer. Browse 270 colored manila folders stock photos and images available, or start a new search to explore more stock photos and images. Two staff members moved the body to an isolation anteroom adjacent to trauma one. They took a blood sample and saw manila-colored particles floating in it. They also noticed strange manila-colored particles floating in the blood. All in all, officials conducted three autopsies on Ramirezs body and concluded that she died of heart failure due to kidney failure brought on by her late-stage cancer. [4] The Livermore scientists postulated on The New Detectives that the change in temperature of the blood drawn, from the 98.6F (37C) of Ramirez's body to the 64 F (18C) of the emergency department, may have contributed to its conversion from DMSO2 into DMSO4. From murderous birds to jellyfish rain, here are several of the strangest theories that have been put forward to explain unsolved mysteries. In real blood those crystals might have appeared manila-colored. Strange orange orbs were sighted by other nearby hikers around the time of the incident that some believe could have been a type of bomb. Instead, Welch says, it smelled like ammonia. But given its potential side effects, its a dangerous remedy because in its readily available hardware- store grease-cutting form, its 99 percent pure. They searched for any of a host of noxious chemicals, including hydrogen sulfide (also known as sewer gas), an insidious poison that smells like rotten eggs and at high concentrations can kill a person after one or two whiffs, and phosgene, a gas with a dual identity on the one hand, a law-abiding ingredient used in the preparation of many organic chemicals, and on the other a terrible weapon for chemical warfare that tears open capillaries in the lungs, drowning its victims in blood. folder with document - colored manila folders stock pictures, royalty-free photos & images. Livermore Labs postulated that Ramirez had been using dimethyl sulfoxide (DMSO), a solvent used as a powerful degreaser, as a home remedy for pain. To refresh Grants memory of the case, he also showed him his results, including the puzzling compounds he had identified. Shortly after that, three of the medics began feeling sick and fainted one after the other. Our colored particles are prepared by polymerizing styrene in oil soluble dye solution in styrene. At 8.50 PM, after 45 minutes of CPR and defibrillation, she was pronounced dead due to kidney failure. A trained forensic eye can quickly dismiss such misleading signals. The clothes of whoever could have been exposed were removed into plastic bags. Lams strange behavior in the elevator has led some to believe that Lam was playing a Korean elevator game. She initially shared a room with strangers, but was moved soon after when the other girls complained about her strange behavior. Yuri Yudin stated that he believed there was an explosion, possibly from a weapons test, and cover-up by the Soviet military. Her name was Gloria Ramirez. The hospital was evacuated except for a few people staying to help Ramirez, but she died forty-five minutes after she arrived at the hospital from complications of cancer. DMSO2 is known to crystallize at room temperature, and crystals were observed in some of Ramirez's drawn blood. The Livermore chemists envision a reaction which hasnt yet been observed in which some of the molecules of dimethyl sulfone in Ramirezs blood broke apart. Rather, the Livermore team thought the more likely event was that Ramirez had rubbed DMSO on herself to relieve the pain from her cancer. Facebook Watch is the place to enjoy videos and shows together. We had a meeting on the very last day of the month to determine our exact game plan, says Brian Andresen, the centers director. But the theory has provoked a backlash from other scientists. Vapors of dimethyl sulfate, the index explained, kill cells in exposed tissues, such as the eyes, mouth, and lungs. The worlds only Antarctic murder mystery remains unsolved. After that, Gorchynski felt nauseated and lightheaded, she left to a nurses desk, and there she fainted too. Buy paint matching this color The solution became supersaturated, and dimethyl sulfone began to form beautiful white crystals, says Whipple, who did the experiment with Grant. But Marks was engaged, seemingly enjoyed his work, and had dozens of other people to socialize with. Bizarre Case of Gloria Ramirez, AKA "The Toxic Lady", Whose Body Emitted Toxic Fumes That Caused the ER Staff to Faint Half an hour later, she woke up to smoke filling the house. This is likely to occur again DMSO is not uncommon, asserts Barry Taylor, a microbiologist at Loma Linda University School of Medicine who has followed the case closely. Abac is an exceptionally strong fibre, nowadays used for special papers like tea bag tissue. As the vapors grew warmer, chemicals began to migrate along the column, sorting out along the way according to their electric charge and vapor pressure. Colored Polystyrene Particles. Get it as soon as Fri, Sep 16. It is sold in gel form at hardware stores and said to have agarlic-like smell, which explains the odor and greasiness of her chest. (A liter of liquid dimethyl sulfate sells for around $32.) Gluons are also colored . Because of concern that the stricken staff had been felled by a noxious chemical, they were stripped down to their underwear, and their clothes were bundled into plastic bags. The medical staff injected her with diazepam, midazolam, and lorazepam to sedate her. [2] Sold in gel form at hardware stores, it could also explain the greasy appearance of Ramirez's body. And thus the macabre chemistry of that night hid most of its traces from investigators. Welch, meanwhile, forced air into Ramirezs lungs with an Ambu-bag, a football-size rubber bladder connected to a plastic mask thats placed over the patients nose and mouth, serving as a sanitary alternative to mouth-to-mouth resuscitation. About 8:15 in the evening on February 19, 1994, paramedics wheeled a young woman into the emergency room of General Hospital in the southern California city of Riverside. They also stated that the cuts on her scalp may have been caused by the owls talons. But other scientists come to Livermores defense. At a press conference on April 29 to reveal the autopsy results, coroner Scotty Hill announced that Ramirez had died of cardiac dysrhythmia triggered by kidney failure stemming from her cervical cancer. Gorchynski, the most severely ill, spent two weeks in intensive care, where in addition to apnea she suffered from hepatitis, pancreatitis, and avascular necrosis, a condition in which bone tissue is starved of blood and begins to die. I remember thinking, How could I spend this much time and not find anything?. They interviewed 34 hospital staff who had been working in the emergency room on February 19. Most patients who show up in an emergency room with such symptoms are elderly people, Welch says. Kane said that her face was burning, and she was put on a gurney and taken from trauma one. I have used it as a solvent up to at least 300 degrees, he says. The Toxic Lady But other factors that correlated with severe symptoms didnt seem to match a scenario in which fumes had been released: the survey found that those afflicted tended to be women rather than men, as well as people who had skipped dinner that evening rather than those who had a full stomach. What had been (CH3)2SO2 became CH3, CH3, and SO2. Up to 600 dogs may have died this way, prompting theories that a supernatural presence may be at play. The state report also angered some of the other emergency room staff, including Welch. Catch her! During the mid-1960s a flurry of research showed it had remarkable healing powers, easing intractable pain and reducing anxiety. Questions were immediately raised over how she made it to the locked rooftop and how she replaced the heavy lid from inside. Researchers Double-Play Cancer Clinical Trials, Dogs May Be Key in Early Bladder Cancer Detection, A Blood Test That Screens For Multiple Cancers At Once Promises To Boost Early Detection, Developing A Drug To Identify And Target Tricky Cancer Cells. The Livermore team was able to cull details about the symptoms of dimethyl sulfate exposure from the reference book, as well as from a safety sheet that accompanies any dimethyl sulfate purchased by industry. She developed hepatitis and avascular necrosis in her knees. Then when I woke up, I couldnt control the movements of my limbs. He was discouraged. The hazmat team was after a smoking gun some volatile toxicant that might yet be lurking in the air of the emergency room. It was one of those deals that was pretty fortuitous, Grant says. Several organic chemists have scoffed at the step-by-step change of DMSO into airborne dimethyl sulfate. At 8:50p.m., after 45 minutes of CPR and defibrillation, Ramirez was pronounced dead from kidney failure related to her cancer. In the end, the Riverside case leaves us with a warning and a puzzle. In DMSO2 form, it is known to crystallize at room temperature, which could explain the manila-colored crystals the blood that was drawn from her body (at 98.6 0F) and into the syringe (at room temperature, 64 0F). [2], Manila paper was originally made out of old Manila hemp ropes which were extensively used on ships, having replaced true hemp. Ive gotten messages on my answering machine from chemists who say its an impossible conclusion, says Andresen. A staff member asked her if she was okay, but before she could respond she also fainted. The standard model is the name given in the 1970s to a theory of fundamental particles and how they interact. Manila paper is buff-colored and the fibers of the paper are usually visible to the naked eye. Jeannie, George, and four of the children escaped. On February 21st, Lams body was found on the roof of the hotel in a water tank. They shot through two sets of double glass doors, veered to their left, and parked her in a small curtained space marked trauma room one. There clearly was something unusual going on, but nothing that could have resulted in Ramirezs death or the emergency room symptoms, Andresen says. The nurse who drew the blood quickly fainted, and soon two other people in the room passed out. Ramirez earned the nickname the Toxic Lady because no one could examine her body without exposing themselves to a wide range of medical problems. Shop Now LRV 68.26 Collection Color Preview Get your own digital color dollop of Manila 2158-50 Create My Dollop Lighting Screen colors may differ. Ochoa lunged for Kane, caught her, and gently guided her limp body to the floor. tough manila colored stock. The crystals of dimethyl sulfone turned into dimethyl sulfate as well and vanished from sight. The medics started standard protocol for her condition by administering fast-acting drugs, Valium, Versed, and Ativan. Sometimes its a pattern that weve never seen before, he says, such as the Riverside case. At 12:30 a.m. Jeannnie answered a phone call from a woman who claimed to have a wrong number. When oxygen was added, it could have become dimethyl sulfone, forming the crystals in Ramirezs blood. It takes a really damn potent toxin to do all that, says Sheldon Wagner, a clinical toxicologist at Oregon State University. On the same page of the index he had been reading, he found the answer: dimethyl sulfate. Marc Micozzi, director of the National Museum of Health and Medicine in Washington, D.C., is one. In January of 1959, ten college students decided to go on a hiking trip in the Ural Mountains of the Soviet Union. Balderas endured bouts of apnea during a ten-day hospitalization. We specialize in products designed for medical facilities, law firms, educational institutions, and more. In 2018, the Canadian government found evidence of brain damage in their diplomats and pulled them from the country as well. Lam appeared to be hiding from someone in the hallway or potentially suffering a mental crisis of some kind. The hotel itself has had a spooky reputation for decades as the site of several suicides and connections to several murders. In court, three experts backed the possibility that an owl had attacked her and caused a deadly fall down the stairs. With this technique, you can layer a single . The Riversides Coroners Office gave the investigation work to Lawrence Livermore National Laboratory, who came up with the DMSO hypothesis. Image Source: brantford Gorchynski shook intermittently; over and over again she would stop breathing for several seconds, take a few breaths, then stop breathing again a condition known as apnea. Catch her! On Christmas Eve, 1945, a fire quickly overtook the home of the Sodder family. This WWII Shipwreck Is Pouring Pollutants Into The North Sea. Its a really clever piece of detective work, says Oregon State toxicologist Frank Dost. Test with samples. Then with an electrical shock from the defibrillator, it could have become dimethyl sulfate, a toxic chemical that could have poisoned the staff. Fourteen months after the incident, the Riverside cases legacy remains peculiar and shadowy. Ochoa ordered the staff to evacuate all emergency room patients to the parking lot outside the hospital. One was an unidentified amine, a derivative of ammonia, that may have contributed to the ammonia-like smell noted in the emergency room. Agents such as lidocaine and Bretylium were given to correct her heartbeat. In the HSL color space #e7c9a9 has a hue of 31 (degrees), 56% saturation and 78% lightness. Maureen Welch, a respiratory therapist who was assisting in the trauma room, was the third to pass out. The Sodders put up a billboard with their childrens pictures and continued searching for them for the rest of their lives. Complaining that she was light-headed, she left the trauma room and sat at a nurses desk. This is where we were afraid we might find a showstopper that would kill the theory, says Grant. In chemistry little changes can sometimes lead to big results. The nurse who replaced her noted that Gloria's blood contained manila-colored particles. Dimethyl sulfate doesnt vaporize easily the Merck Index lists its boiling point as 370 degrees. Here finally was a chemical that could cause some real damage. People who had worked within two feet of Ramirez and had handled her intravenous lines had been at high risk. We just wanted the coroners offices opinion, and they took it and said, This is the answer. It caught us way off guard. Many sleuths have come to believe that the children were kidnapped in a revenge plot. One of the harshest critics of the Livermore theory is a scientist who did much of the clinical research on DMSO in the early 1960s. They stripped off her shirt and pressed padded electrodes against her chest; at that point several people saw an oily sheen covering Ramirezs body, and some noticed a fruity, garlicky odor that they thought was coming from her mouth. This, however, has not been confirmed. They conducted an experiment to see how much dimethyl sulfone could accumulate in the blood at normal body temperature. The shattering pattern, unique to every substance, is called a mass spectrum. Welch called Andresen at Livermore and implored him to take another look. As the syringe filled, Kane noticed a chemical smell to the blood. Stansberry was being investigated for financial crimes at the time of Riveras death and placed a gag order on his employees during the investigation. Finally, the electric shocks during defibrillation could have converted DMSO2 to DMSO4, exposure to which could have caused the symptoms among those who were in the vicinity. Twenty-three people eventually reported symptoms. The second nurse fainted too and later a respiratory therapist was the third to pass out. file security - colored manila folders stock illustrations. Her blood also alarmingly smelled like ammonia. You can help Wikipedia by expanding it. Since DMSO can react with oxygen and form dimethyl sulfone, Grant began to wonder what other compounds might be formed when oxygen is added to the chemical. She was taking shallow, rapid breaths. Nevertheless, according to Grant and other chemists, some fraction will still vaporize at room temperature. With the rise of internet sleuths, true crime podcasts and videos, and discussion forums, its safe to say that many people love speculating about real-life mysteries. Social media has allowed people from around the world to connect and share ideas on bizarre occurrences that have puzzled investigators. An emergency room entrance. Canadian college student Elisa Lam checked into the Cecil Hotel in Los Angeles on January 28th, 2013. In one, Ramirez spread a cream on her skin that contained phencyclidine (better known as PCP, or angel dust) dissolved in a DMSO carrier base (a common way to take the drug). But in the past decade, as the production of nuclear weapons has tapered off, Livermore and its fellow labs have attempted to find an identity better suited to a post- cold war world. The ropes were made from abac or Musa textilis, which is grown in the Philippines;[3] hence the association with Manila, its capital city. Andresen suspected that the headspace would be a likely retreat for a noxious gas particularly in the container holding the bile, a yellowish secretion of the liver, where poisons often concentrate. When it became clear that Ramirez was responding poorly to treatment, the staff tried to defibrillate her heart with electricity. She had been admitted to the emergency department while suffering from late-stage cervical cancer. More recently new woodpulp has often been replaced with a high proportion of recycled fibers. Realizing dimethyl sulfate was their best lead yet, Richard Whipple and Jeffrey Haas, chemists at the forensic center, searched among the thousands of papers that have been written about these compounds. There were also injuries on the back of her head consistent with blunt force, and the coroner stated that he believed she had not died from a fall, but may have been beaten. First on the scene, arriving at the hospital at around 11 p.m., was a Riverside County hazardous materials team. Authorities have disputed the helicopter idea because there was no noise reported at the time, the location was too low to allow helicopters in the airspace, and the nearby harbor would have been a better location to dispose of a body. She was now the second member of the Riverside emergency room staff being wheeled away from the trauma room on a gurney. One thing, however, is certain: several days after the autopsy, the Riverside coroner had still found nothing remarkable and had begun to solicit help. Police released strange footage of Elisa ducking in and out of an elevator at the hotel shortly before her disappearance. Several hikers were only in their underwear. She was sedated and then defibrillated by doctors, who noticed that her body was covered in an oily sheen. The Livermore scientists do offer a cautionary note in their report, which recommends that hospitals be made aware of the possible consequences of such a chemical reaction occurring in their emergency rooms. [2][3] The Livermore scientists theorized that the DMSO in Ramirez's system might have built up owing to urinary blockage caused by her kidney failure. Ochoa and three others repeatedly administered electric shocks and drugs, but their efforts to stabilize Ramirez failed. The tent was sliced open from the inside. Medical personnel think of sterile as being without bugs, not without chemicals, Andresen says. To help lure him back to the case, she sent him a copy of a scrapbook of material she had accumulated, including news stories, the Riverside coroners report, legal briefs, and toxicology reports. Georges ladder was missing. Manila paper is buff-colored and the fibers of the paper are usually visible to the naked eye. Translation Context Grammar Check Synonyms Conjugation. While treating Ramirez, several hospital workers fainted and others experienced symptoms such as shortness of breath and muscle spasms. In the RGB color model #e7c9a9 is comprised of 90.59% red, 78.82% green and 66.27% blue. The forensic center took up the Ramirez case in early March, when a Sacramento criminologist put the Riverside Coroners Office in touch with the centers deputy director, Pat Grant. Gorchynski had to spend two weeks in intensive care and use crutches for two months. By the time she got to the emergency room, she was in a confused state and already suffering from abnormal heart rate and breathing. But Lams case is one of the most bizarre. But even though theres no way to prove Livermores scenario, I think they gave us a report thats quite interesting and analytical, he says. They dissolved the compound in a transparent liquid called Ringers solution, which is basically all the ingredients of blood minus red blood cells. Potential military bombings of a nearby lake could have sent jellyfish material into the air and caused it to mix with rain clouds. The riverside coroners office felt it had reached the end of the road, too. The small, brightly colored particlesoften stick to clothing, skin, and furniture, and can be a hassle to remove. And despite their desire to press forward, they had to put the Ramirez case on the back burner for the rest of September. Printed on 2 sides in black ink. The team would also check for any gases that may have vented off the samples into the headspace, the pocket of air separating the samples from the tops of their containers. She passed the syringe to Julie Gorchynski, a medical resident who noticed unusual manila-colored particles floating in the blood an observation echoed by Humberto Ochoa, the doctor in charge of the emergency room, who was helping treat Ramirez. Colored particles are prepared by polymerizing styrene in oil soluble dye solution styrene... Whoever could have been caused by the owls talons sulfate as well of 's. Work to Lawrence Livermore National Laboratory, who noticed that her face was burning, and,... Order on his employees during the mid-1960s a flurry of research showed it had remarkable healing powers, intractable..., CH3, CH3, CH3, and there she fainted too blood sample and saw manila-colored particles in. Said that her body was covered in an emergency room with such symptoms are elderly people, Welch says it. Theory, says Andresen % saturation and 78 % lightness big results students decided go... 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