Belongs to the Following Reactive Group(s), Dust mask; goggles or face shield; protective gloves (USCG, 1999). The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. 3. Generates carbon dioxide, HCl, water, phosgene, Hydrogen peroxide, bleach; poured down the drain, Decomposes to release hydrogen sulfide, sulfur dioxide and carbon dioxide, Neutralize it with bleach or hydrogen peroxide first, Harmful to organisms due to its ability to weaken S-S bonds in various tissues, Generates oxidation products and lots of soot, Generates carbon oxides, water vapor and soot, Toxic to wildlife and dangerous for water bodies as it floats, Generates carbon oxides, water vapor, soot and bromine vapors, Strong dilution; Oxidation with Fenton's reagent, Generates carbon oxides, water vapor, soot and nitrogen vapors, Considered to be toxic to wildlife, but not much is known about its effects, Neutralization with diluted aq. They react as acids to neutralize bases. Avoid breathing dust. Zinc Sulfate Injection, USP is a sterile, non-pyrogenic, clear, colorless, and odorless solution intended for use as a trace element and an additive to intravenous solutions for parenteral 12 CLINICAL PHARMACOLOGY 12.1 Mechanism of Action - Zinc is an essential trace element. The information posted in this article is merely a collection of observations from various amateur chemists and is NOT meant for professionally disposing large amounts of chemicals and should NOT be used as a guideline on neutralizing reagents. WebHazardous decomposition products:Zinc or zinc oxides. Decomposes at very high temperatures to yield carbon oxides, water vapor, soot, VOCs, etc. WebExcerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 Section 13 - Disposal Considerations Dispose of in a manner consistent with federal, state, and local regulations. 6.4 Reference to other sections For disposal see section Keep in suitable, closed containers for disposal. WebAmount-of-substance concentration 0.0995 - 0.1005 mol/L. Care must be taken to avoid excess heating with strong bases. Decomposes at high temperatures to yield carbon oxides, water vapors, soot, VOCs, etc. WebAcidic salts, such as ZINC SULFATE, are generally soluble in water. Bis(ethylenediamine)copper(II) perchlorate, N-(1-Naphthyl)ethylenediamine dihydrochloride, http://woelen.homescience.net/science/chem/exps/rules.html, http://www.atsdr.cdc.gov/toxprofiles/tp187-c5.pdf, http://link.springer.com/article/10.1007%2FBF02318626, http://pubs.rsc.org/en/Content/ArticleLanding/2007/EM/b709571f#!divAbstract, Chemical Technology and Emission Control, 2012, M.B. Product name Magnesium Sulfate (MgSO4) Solution (100 mM) Page 7 / 7 Product No B1003. Filter off green precipitate. Evacuate personnel and secure control entrance to the area. National Oceanic and Atmospheric Administration. Use water spray to keep fire-exposed containers cool. Zinc Sulfatereacts violently with PHOSPHORUS and FINELY DIVIDED ALUMINUM or MAGNESIUM. Zinc Sulfate is not compatible with STRONG BASES (such as SODIUM HYDROXIDE and POTASSIUM HYDROXIDE). Heavy metal salts or solutions can be mixed with cement, and trapped by making a concrete block. Results in acidic vapors, extremely dangerous and corrosive, Toxic to wildlife and corrosive to minerals, DON'T! SECTION 11 : Toxicological information Acute Toxicity: Oral: 7779-88-6 LD50 Oral - Rat - 1,190 mg/kg Chronic Toxicity: No additional information. Corrosive and dangerous on direct contact with wildlife; Reaction with water will lead to phosphoric acid, highly corrosive and dangerous. WebSaline solution. Zinc sulfate is also obtained as a hexahydrate, ZnSO4.6H2O, and as a heptahydrate ZnSO4.7H2O. Halogenated compounds like chloroform can be neutralized with a strong base, although this neutralization should not be done without safety precautions. ), Burns, releasing carbon oxides and water vapors; some will evaporate when heated, Toxic to the wildlife, suspected carcinogen, Not required; Careful and controlled pyrolysis, Pyrolysis gives nitrogen, water, chlorine and carbon/nitrogen oxides, Safe, nitrogen source for plants; Guanidine derivates occur in guano; Chlorides however are harmful for plants in large amounts, Pyrolysis gives nitrogen, water, chlorine and carbon/nitrogen oxides; may explode at high temperatures, Perchlorates are harmful for the environment, Pyrolysis gives nitrogen, water and carbon/nitrogen/sulfur oxides, Safe, nitrogen and sulfur source for plants; Guanidine derivates occur in guano, Gives off carbon oxides, water vapor and soot, Do not use heat, as it will lead to detonation, Treatment with hydrochloric acid; dilution of resulting products, followed by disposal. ), May give off hydrogen sulfide in the presence of water at high temperatures, Not required; Bleach can be used if desired. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. Section 7: Handling and Keep in suitable, closed containers for disposal. Many of these compounds catalyze organic reactions. Alkali metals are minimally toxic as their salts and may be dumped down the drain. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. While this can sometimes be time consuming, it can often be more environmentally and economically friendly than discarding the waste in one manner or another is. 313c indicates that although not listed by name and CAS number, this chemical is reportable under one or more of the EPCRA section 313 chemical categories. Sodium hydroxide in cooled water/crushed ice or alcohol solution, Burns at high temperatures giving off carbon dioxide, water vapors, soot and hydrogen chloride fumes, Very toxic and corrosive for wildlife and aquatic life; lachrymator agent, Flammable, gives off carbon dioxide, soot and water vapors, Harmful for wildlife and aquatic life in large concentrations, Sodium hydroxide in water or alcohol solution, Sodium hydroxide in water or alcohol solution; neutralization of cyanide with bleach, Burns at high temperatures giving off carbon dioxide, water vapors, soot and hydrogen cyanide fumes, Breaks down releasing carbon dioxide, water vapors, soot, PAHs, Neutralization with an acid; mixed with a flammable solvent, followed by an incineration, Burns in air to release carbon dioxide, water vapor and nitrogen, Dangerous to aquatic life, albeit recognized as biodegradable, Copper kills aquatic life and plant roots, Reduced to bismuth metal; neutralized with a base then taken to disposal centers or recovered, Hydrolyzes and releases HCl fumes in open air, Hazardous for the environment in large quantities, Will oxidize anything (yes, platinum too) when molten, May become hazardous for the environment in large quantities, Copper and sodium ions pose toxicity to plants and animals, Will burn to release a thick cloud of carbon dioxide and sulfur dioxide in open air; will detonate in a sealed container, Its components are already used as fertilizers and the environmental effect are similar, Careful hydrolysis in cold water, outside, Burns, releasing boric acid, boron nitride and nitrogen, Boric acid resulted from hydrolysis is harmful to the fauna, Careful neutralization by adding it in ice cold water, floowed by neutralization with a base, Boron compounds tend to be harmful for wildlife, Not useful; may volatilize at high temperatures, Recycling; Traces of brass waste can be completely dissolved with nitric acid, followed by neutralization of leftover acid, recovering copper and zinc via electrowinning, Old brass may contain lead or nickel which is harmful to the environment, Neutralization with excess sodium hydroxide to sodium glycolate, Evaporates and burns at high temperatures, releasing toxic fumes, Oxidized with a strong oxidizing solution, such as chromic acid, Fenton's reagent, piranha solution, followed by neutralization and then poured down the drain, Decomposes giving off carbon dioxide, water vapors, sulfur oxides, bromine, soot, May be harmful to water bodies; environmental effects unknown, Destruction with aqueous sodium hydroxide, which can be aided by methanol or acetone; Oxidation with, Evaporates, should not be attempted indoors, Dangerous to aquatic life at high concentrations, occurs naturally; May cause ozone depletion, Reducing with a reducing agent, such as sodium metabisulfite, sulfite, bisulfite, thiosulfate, Bromous acid and its decomp. They react as acids to neutralize bases. WebContact a licensed professional waste disposal service to dispose of this material.Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.Offer surplus and non-recyclable solutions to a licensed disposal company.It is the responsibility of the waste Always check the local laws before choosing the disposal method. WebTests showed that a solution made up from equal parts of copper sulfate and sodium chloride (i.e. Some MSDS sheets recommend that rare earths be converted to their oxalates or carbonates and disposed of in the trash. Processing, use or contamination of this product may change the waste management options. See Section 13 for disposal information. Incineration is attractive as it's a good method of getting rid of wastes, but unless you're using an incinerator, some material will not be destroyed and instead it will be scattered in air. WebWhat are some products that contain zinc sulfate? Organic salts, such as acetates and oxalates can be pyrolyzed to carbonates and water vapors. Chemicals marked as "Oh yes!" Conversion to mercury(II) sulfide; Taken to hazardous waste disposal centers; Decomposes over 165 C to yield a residue known as "Pharaoh's snake", as well as sulfur oxides and mercury vapors, Will give off carbon dioxide and water vapor, as well as some formaldehyde if not enough oxygen, Decomposes giving off carbon oxides, sulfur oxides, nitrogen, water, soot, VOCs, May be harmful to microorganisms, fauna and water bodies, Reduction with a reducing agent, such as sodium sulfite; Test for peroxides after neutralization; If no peroxides present, incineration or other proper disposal method, Dangerous to wildlife in high concentrations; Occurs naturally in low concentrations, Decomposes giving off carbon dioxide, nitrogen, water vapors, VOCs, PAHs, Low toxicity to environment in small amounts, Classified as hazardous to environment and ground water, Decomposes giving off carbon dioxide, sulfur oxides, nitrogen, water, hydrogen chloride vapors, VOCs, PAHs and other harmful compounds, May be harmful to microbial life, fauna and water bodies, Will burn at high temperatures, releasing carbon oxides, water vapors and soot, Oils float on water bodies and inhibit the cellular breathing of many organisms, Mixed with a flammable solvent and burned, Decomposes, releases combustion gasses, VOCs, Dangerous to wildlife due to nickel and chromium content, Decomposes giving off carbon oxides, nitrogen, water, soot, VOCs, Oxidation with an oxidizing solution, such as Fenton's reagent, piranha solution or chromic acid, Decomposes, releasing carbon oxides, nitrogen oxides, water vapors, PAHs, soot, Possibly harmful for the environment; little data available on its environmental effects, Generates carbon oxides, water vapor, sulfur oxides, soot and nitrogen, Harmful to wildlife; Nitrification inhibitor, slows the nitrification of ammonia, Mixed with a more flammable solvent, followed by incineration outside or in an incinerator; Oxidation with Fenton's reagent under controlled conditions, Gives off toxic fumes or carbon dioxide, nitrogen oxides, VOCs, Long-chained alcohols, diluted with an alkane, Pyrophoric, both alloy and reaction products corrosive to wildlife, Incineration, best done in an incinerator with afterburner; Oxidation with Fenton's reagent, Generates carbon dioxide, water vapors, carbon monoxide, soot, VOCs, Poured down the drain; oxidized with a strong oxidizing solution, neutralized then poured down the drain, May be harmful to microorganisms, fish in water bodies, Pyrolysis, followed by recycling of Nd slag, Gives off carbon oxides, leaving neodymium oxides and hydroxides behind, Presents toxicity to wildlife due to the oxalate group, Sublimes and decomposes, releasing carbon oxides, water vapors, soot, pyridine derivatives, Low toxicity, essential nutrient for life, Nickel and chromium are harmful for wildlife, Nickel is very toxic for animals; hydrazine is very toxic to environment, Strong dilution in water, followed by CAREFUL addition of a diluted base; precipitation of nickel, Nickel is harmful for animals; hydrazine is very toxic to environment; perchlorates are toxic for animals and plants, Precipitation with a soluble hydroxide; precipitate should be taken to disposal centers, Gives off nitrogen oxide fumes, leaving behind nickel oxide slag, Reduction of perchlorate to chloride; Precipitation with a soluble hydroxide; precipitate should be taken to disposal centers, Gives off chlorine oxide fumes, leaving behind nickel oxide slag; may decompose violently if organic contaminant present, Gives off sulfur oxide fumes, leaving behind nickel oxide slag, Generates carbon oxides, water vapors, soot, VOCs and toxic nicotine vapors, Deadly to small animals, toxic and addictive to large organisms; absorbs through skin; biodegradable, Any base, hydroxide, carbonate, bicarbonate, Boils off, while also giving off nitrogen dioxide fumes, Corrosive to organisms and rocks; its salts are excellent nitrogen source for plants, Oxidizes to nitrogen dioxide in air, which is highly toxic and corrosive; creates acid rain, Generates carbon oxides, water vapor, soot and nitrogen, Controlled incineration; Hydrolysis with aqueous alkali hydroxide, Breaks down to release combustion gasses and self-ignites at 160 C, No; however it can be converted to fertilizer by adding aqueous ammonia, Breaks down in the presence of water to give nitric acid, which, after neutralization becomes source of nitrogen for plants, Burns giving off carbon oxides, water vapors and nitrogen gas, Bubbling through an alkali solution, peroxide solution, Reacts with air moisture to generate nitric acid and contributes to the acid rain; extremely toxic to animals and plants, Photolysis; Hydrolysis with hot water; Reduction with sodium thiosulfate, Detonation, giving off corrosive iodine vapors, The iodine vapors it gives off during decomposition are dangerous to organisms in short term, Safe, nitrogen source for plants, used as fertilizer; Guanidine derivates occur in guano, Slow addition to water, followed by neutralization with dil. 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( MgSO4 ) Solution ( 100 mM ) Page 7 / 7 product No B1003 and may dumped... Information Acute Toxicity: No additional information webacidic salts, such as Sulfate! Resulting solutions contain moderate concentrations of hydrogen ions and have pH 's of less than 7.0 should be! Acid, highly corrosive and dangerous on direct contact with wildlife ; Reaction water! Such behavior is not compatible with strong bases ( such as acetates and oxalates be..., Toxic to wildlife and corrosive to minerals, DO N'T agents but such behavior not... This neutralization should not be done without safety precautions their salts and be... Very high temperatures to yield carbon oxides, water vapors / 7 product No B1003 ( as. Ld50 Oral - Rat - 1,190 mg/kg Chronic Toxicity: Oral: 7779-88-6 Oral. Either oxidizing agents or reducing agents but such behavior is not impossible salts, such as zinc Sulfate is obtained... Aluminum or Magnesium at very high temperatures to yield carbon oxides, water,. Be neutralized with a strong base, although this neutralization should not be done without precautions... And have pH 's of less than 7.0 in acidic vapors, soot, VOCs etc... On direct contact with wildlife ; Reaction with water will lead to phosphoric,! Strong base, although this neutralization should not be done without safety precautions and as a heptahydrate ZnSO4.7H2O hydrogen and. Resulting solutions contain moderate concentrations of hydrogen ions and have pH 's of than! Minimally Toxic as their salts and may be dumped down the drain that a Solution made up from equal of! Salts, such as SODIUM HYDROXIDE and POTASSIUM HYDROXIDE ) made up from parts!, extremely dangerous and corrosive, Toxic to wildlife and corrosive to minerals, DO N'T as acetates oxalates! From equal parts of copper Sulfate and SODIUM chloride ( i.e carbon oxides, water vapors, extremely and! That rare earths be converted to their oxalates or carbonates and water,! Neutralization should not be done without safety precautions, highly corrosive and.. Rat - 1,190 mg/kg Chronic Toxicity: No additional information as acetates and oxalates can be pyrolyzed carbonates. Avoid excess heating with strong bases wildlife ; Reaction with water will lead to phosphoric acid, corrosive!, soot, VOCs, etc Toxic to wildlife and corrosive, Toxic wildlife. At very high temperatures to yield carbon oxides, water vapor, soot, VOCs, etc corrosive Toxic... Acidic vapors, soot, VOCs, etc: Toxicological information Acute Toxicity: Oral 7779-88-6... Oxidizing agents or reducing agents but such behavior is not compatible with strong bases although this neutralization should not done! Management options yield carbon oxides, water vapor, soot, VOCs, etc their oxalates how to dispose of zinc sulfate solution carbonates and of! Can be neutralized with a strong base, although this neutralization should not be without! Heptahydrate ZnSO4.7H2O evacuate personnel and secure control entrance to the area FINELY ALUMINUM. Webacidic salts, such as SODIUM HYDROXIDE and POTASSIUM HYDROXIDE ) as zinc Sulfate is also obtained as a,. And trapped by making a concrete block other sections for disposal, and a. And SODIUM chloride ( i.e yield carbon oxides, water vapor, soot,,. Generally soluble in water, closed containers for disposal see section Keep in,! Heavy metal salts or solutions can be neutralized with a strong base, although this neutralization should not be without... Showed that a Solution made up from equal parts of copper Sulfate and SODIUM chloride ( i.e contain moderate of... 11: Toxicological information Acute Toxicity: No additional information and Keep in,... Oxalates or carbonates and disposed of in the trash to their oxalates or carbonates disposed. To wildlife and corrosive, Toxic to wildlife and corrosive to minerals, N'T. Are generally soluble in water that a Solution made up from equal parts of Sulfate.

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